N-Boc-N-methyl-(R)-2-allylglycine is a noncanonical amino acid with an allylic side chain and N-methyl substitution, engineered for backbone and side-chain modulation. The Boc group permits orthogonal protection strategies in SPPS. Researchers incorporate the residue to introduce alkene handles for metathesis or click-type transformations. Applications include stapled-peptide design, conformational locking, and late-stage functionalization.
1. High fat diet and GLP-1 drugs induce pancreatic injury in mice
5. TMEM16F and dynamins control expansive plasma membrane reservoirs
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